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Morrison and Boyd Organic Chemistry pdf
Role of the Solvent Secondary Bonding
7. 1 Role of the solvent 249
12 Secondary bonding 250
7.3 Solubility: non-ionic solutes 252
7.4 Solubility: ionic solutes. Protic and aprotic solvents. Ion pairs 254
7.5 The SnI reaction: role of the solvent. Ion-dipole bonds 258
7.6 The Sn 2 reaction: role of the solvent. Protic and aprotic
solvents 261
7.7 The Sn 2 reaction: phase-transfer catalysis 264
7.8 Sn2 vs. SnI: Effect of the solvent 267
7.9 Solvolysis. Nucleophilic assistance by the solvent 268
7.10 The medium: a message 271
Preparation of alcohols 222 Reactions of alcohols 224
-: 1 Alcohol as acids and bases 227
6 .13 Reaction of alcohols with hydrogen halides. Acid catalysis 229
6 .14 Formation of alkyl sulfonates 233
6. 1 5 Oxidation of alcohols 235
ETHERS
6. 16 Structure and nomenclature of ethers 237
6. 17 Physical properties of ethers 238
6. 1 8 Industrial sources of ethers. Dehydration of alcohols 238
6.19 Preparation of ethers 240
6.20 Preparation of ethers. Williamson synthesis 241
6.21 Reactions of ethers. Cleavage by acids 242
6.22 Analysis of alcohols 243
6.23 Analysis of Ethers 244
7 Role of the Solvent Secondary Bonding
7. 1 Role of the solvent 249
12 Secondary bonding 250
7.3 Solubility: non-ionic solutes 252
7.4 Solubility: ionic solutes. Protic and aprotic solvents. Ion pairs 254
7.5 The SnI reaction: role of the solvent. Ion-dipole bonds 258
7.6 The Sn 2 reaction: role of the solvent. Protic and aprotic
solvents 261
7.7 The Sn 2 reaction: phase-transfer catalysis 264
7.8 Sn2 vs. SnI: Effect of the solvent 267
7.9 Solvolysis. Nucleophilic assistance by the solvent 268
7.10 The medium: a message 271,
8 Alkenes I. Structure and Preparation Elimination
8.1 Unsaturated hydrocarbons 273
8.2 Structure of ethylene. The carbon-carbon double bond 273
8.3 Propylene 276
8.4 Hybridization and orbital size 276
8.5 The butylenes 277
8.6 Geometric isomerism 279
8.7 Higher alkenes 282
8.8 Names of alkenes 282
8.9 Physical Properties 283
v 10 The organic chemistry of vision 285 Industrial sources 287 « .2 Preparation 287
» – Dehydrohalogenation of alkyl halides: 1,2-elimination 290
* – Kinetics of dehydrohalogenation. Duality of Mechanism 293
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